Multi-color UCNPs/CsPb(Br_1-xI_x)₃ for upconversion luminescence and dual-modal anticounterfeiting

Abstract

Advanced hybrid materials have attracted extensive attention in optoelectronics and photonics application due to their unique and excellent properties. Here, the multicolor upconversion luminescence properties of the hybrid materials composed of CsPbX 3 (X = Br/I) perovskite quantum dots and upconversion nanoparticles (UCNPs, core-shell NaYF 4 :25%Yb 3+ ,0.5%Tm 3+ @NaYF 4 ) is reported, achieving the upconversion luminescence with stable and bright of CsPbX 3 perovskite quantum dots under 980 nm excitation. Compared with the nonlinear upconversion of multi-photon absorption in perovskite, UCNPs/CsPbX 3 achieves lower power density excitation by using the UCNPs as the physical energy transfer level, meeting the demand for multi-color upconversion luminescence in optical applications. Also, the UCNPs/CsPbX 3 combined with ultraviolet curable resin (UVCR) shows excellent water and air stability, which can be employed as multicolor fluorescent ink for screen printing security labels. Through the conversion strategy, the message of the security labels can be encrypted and decrypted by using UV light and a 980 nm continuous wave excitation laser as a switch, which greatly improves the difficulty of forgery. These findings provide a general method to stimulate photon upconversion and improve the stability of perovskite nanocrystals, which will be better applied in the field of anti-counterfeiting.