Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction

Abstract

In this work, a CdS/BiVO₄ step-scheme (S-scheme) heterojunction with self-photothermally enhanced photocatalytic effect was synthesized and applied for efficient U(VI) photoextraction. Characterizations such as transient absorption spectroscopy and Tafel test together confirmed the formation of S-scheme heterojunctions, which allows CdS/BiVO₄ to avoid photocorrosion while retaining the strong reducing capacity of CdS and the oxidizing capacity of BiVO₄. Experimental results such as radical quenching experiments and electron spin resonance show that U(VI) is rapidly oxidized by photoholes/^•OH to insoluble UO₂(OH)₂ after being reduced to U(IV) by photoelectrons/^•O₂ ^-, which precisely avoids the depletion of electron sacrificial agents. The rapid recombination of electron-hole pairs triggered by the S-scheme heterojunction is found to release large amounts of heat and accelerate the photocatalysis. This work offers a new enhanced strategy for photocatalytic uranium extraction and presents a direction for the design and development of new photocatalysts.