21:T493,The conventional bulk-boundary correspondence directly connects the number of topological edge states in a finite system with the topological invariant in the bulk band structure with periodic boundary condition (PBC). However, recent studies show that this principle fails in certain non-Hermitian systems with broken reciprocity, which stems from the non-Hermitian skin effect (NHSE) in the finite system where most of the eigenstates decay exponentially from the system boundary. In this work, we experimentally demonstrate a 1D non-Hermitian topological circuit with broken reciprocity by utilizing the unidirectional coupling feature of the voltage follower module. The topological edge state is observed at the boundary of an open circuit through an impedance spectra measurement between adjacent circuit nodes. We confirm the inapplicability of the conventional bulk-boundary correspondence by comparing the circuit Laplacian between the periodic boundary condition (PBC) and open boundary condition (OBC). Instead, a recently proposed non-Bloch bulk-boundary condition based on a non-Bloch winding number faithfully predicts the number of topological edge states.22:T4dc,In the process of oxygen evolution reaction (OER) on perovskite, it is of great significance to accelerate the hindered lattice oxygen oxidation process to promote the slow kinetics of water oxidation. In this paper, a facile surface modification strategy of nanometer-scale iron oxyhydroxide (FeOOH) clusters depositing on the surface of LaNiO₃ (LNO) perovskite is reported, and it can obviously promote hydroxyl adsorption and weaken Ni-O bond of LNO. The above relevant evidences are well demonstrated by the experimental results and DFT calculations. The excellent hydroxyl adsorption ability of FeOOH-LaNiO₃ (Fe-LNO) can obviously optimize OH^- filling barriers to promote lattice oxygen-participated OER (LOER), and the weakened Ni-O bond of LNO perovskite can obviously reduce the reaction barrier of the lattice oxygen participation mechanism (LOM). Based on the above synergistic catalysis effect, the Fe-LNO catalyst exhibits a maximum factor of 5 catalytic activity increases for OER relative to the pristine perovskite and demonstrates the fast reaction kinetics (low Tafel slope of 42 mV dec^-1) and superior intrinsic activity (TOFs of ~40 O₂ S^-1 at 1.60 V vs. RHE).23:T549,Niacin metal-organic frameworks (MOFs) encapsulated microcapsules with alginate shells and copper-/zinc-niacin framework cores were in situ synthesized by using a microfluidic electrospray approach for wound healing. As the alginate shells were bacteria-responsively degradable, the niacin MOFs encapsulated microcapsules could intelligently, controllably, and programmably release calcium, copper, and zinc ions, depending on the degree of infections. The released ions could not only kill microbes by destroying their membrane and inducing the outflow of nutrient substance, but also activate copper/zinc superoxide dismutase (Cu/Zn-SOD) to eliminate oxygen free radicals and rescue the cells from oxidative stress injury. Furthermore, the simultaneously released niacin could promote hemangiectasis and absorption of functional metal ions. Thus, the niacin MOFs encapsulated microcapsules were imparted with outstanding antibacterial, antioxidant, and angiogenesis properties. Based on an in vivo study, we have also demonstrated that the chronic wound healing process of an infected full-thickness skin defect model could be significantly enhanced by using the niacin MOFs encapsulated microcapsules as therapeutic agent. Therefore, the microfluidic electrospray niacin MOFs encapsulated microcapsules are potential for clinical applications.24:T66c,

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