Organic Chemistry Frontiers · 2022 · 21 citations · 54 references
Asymmetric α-C–h AlkenylationEnantioselective SynthesisDerivativesAlkene MetathesisChiral Aryl 1,3-DienesOrganic ChemistryAxial ChiralityChemistryAsymmetric CatalysisAryl Alkenes
An asymmetric α-C–H alkenylation of aryl alkenes has been disclosed to provide axially chiral aryl 1,3-dienes, proceeding through six-membered exo -cyclopalladation, assisted by an aldehyde/ l - t -leucine derived transient chiral auxiliary.
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Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions
Denise A. Colby, Andy S. Tsai, Robert G. Bergman et al. · Accounts of Chemical Research · 2011 · 1.4K citations
Functionalization of C(sp <sup>3</sup> )–H bonds using a transient directing group
Fang‐Lin Zhang, Kai Hong, Tuanjie Li et al. · Science · 2016 · 679 citations · Full text