20:T521,In this study, X-ray photoelectron spectroscopy (XPS) was used to study chitosan-graphene oxide (chitosan-GO) incorporated with 4-(2-pyridylazo)resorcinol (PAR) and cadmium sulfide quantum dot (CdS QD) composite thin films for the potential optical sensing of cobalt ions (Co²⁺). From the XPS results, it was confirmed that carbon, oxygen, and nitrogen elements existed on the PAR-chitosan-GO thin film, while for CdS QD-chitosan-GO, the existence of carbon, oxygen, cadmium, nitrogen, and sulfur were confirmed. Further deconvolution of each element using the Gaussian-Lorentzian curve fitting program revealed the sub-peak component of each element and hence the corresponding functional group was identified. Next, investigation using surface plasmon resonance (SPR) optical sensor proved that both chitosan-GO-based thin films were able to detect Co²⁺ as low as 0.01 ppm for both composite thin films, while the PAR had the higher binding affinity. The interaction of the Co²⁺ with the thin films was characterized again using XPS to confirm the functional group involved during the reaction. The XPS results proved that primary amino in the PAR-chitosan-GO thin film contributed more important role for the reaction with Co²⁺, as in agreement with the SPR results.21:T539,Flexible ultraviolet (UV) photodetectors are considered as potential building blocks for future-oriented photoelectric applications such as flexible optical communication, image sensors, wearable devices and so on. In this work, high-performance UV photodetector was fabricated via a facile combination of single ZnO microwire (MW) and p-type polyaniline. Due to the formation of effective organic/inorganic p-n junction, the as-prepared flexible UV photodetector based on ZnO MW/polyaniline hybrid heterojunction exhibits high performance (responsivity ∼ 60 mA/W and detectivity ∼ 2.0 ×10¹¹ Jones) at the reverse bias of -1 V under the UV illumination. The ZnO MW/polyaniline photodetector displays short response/recovery times (∼ 0.44 s/∼ 0.42 s), which is less than that of most reported UV photodetectors based on ZnO/polymer heterojunction. The fast response speed and recovery speed can be attributed to the high crystallinity of ZnO MW, built-in electric field in space-charge region and the passivation of oxygen traps on the surface. Further, the photodetector using ZnO MW/polyaniline junctions shows excellent flexibility and stability under bent conditions. This work opens a new way to design next-generation high-performance, low-cost and flexible optoelectronic devices for lab-on-a-chip applications.

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