Heat Capacities, Excess Enthalpies, and Volumes of Mixtures Containing Cyclic Ethers. 4. Binary Systems 1,4-Dioxane + 1-Alkanols

Abstract

Excess molar volumes and isobaric excess molar heat capacities for 1,4-dioxane + 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, 1-nonanol, and 1-decanol and excess molar enthalpies for the binary mixtures 1,4-dioxane + methanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, 1-nonanol, and 1-decanol at the temperature 298.15 K have been determined as a function of mole fraction. The magnitude of these experimental quantities is discussed in terms of the nature and type of intermolecular interactions in binary mixtures. When available, the results have been compared with literature values.