Heat Capacities, Excess Enthalpies, and Volumes of Mixtures Containing Cyclic Ethers. 2. Binary Systems 1,3-Dioxolane + <i>n</i>-Alkanes

Abstract

Excess molar volumes for {1,3-dioxolane + heptane, octane, nonane, and decane} at the temperatures 288.15 K, 298.15 K, and 308.15 K, excess molar enthalpies for {1,3-dioxolane + heptane, octane, nonane, decane, dodecane, and tetradecane} at the temperature 298.15 K, and isobaric excess molar heat capacities for {1,3-dioxolane + heptane, octane, nonane, and decane} at the temperature 298.15 K have been determined as a function of mole fraction. The magnitude of these experimental quantities is discussed in terms of the nature and type of intermolecular interactions in binary mixtures.