Journal of Advanced Ceramics · 2021 · 92 citations · 38 references
Natural SciencesMaterials EngineeringMaterials ScienceCeramicsElectronic MaterialsOptical MaterialsColor RenderingLight SourcesLight-emitting DiodesLighting MaterialsLuminescent MaterialsOptical CeramicsConvertersLight-emitting Diode MaterialsLuminescence MechanismsLuminous MaterialsThermal StabilityTransparent CeramicsWhite Light-emitting DiodesWhite-light Emitting Materials
Abstract Realizing a high color rendering index (CRI) in Ce:LuAG transparent ceramics (TCs) with desired thermal stability is essential to their applications in white LEDs/LDs as color converters. In this study, based on the scheme of configuring the red component by Cr 3+ doping, an efficient spectral regulation was realized in Ce,Cr:LuAG TCs. A unilateral shift phenomenon could be observed in both photoluminescence (PL) and photoluminescence excitation (PLE) spectra of TCs. By constructing TC-based white LED/LD devices in a remote excitation mode, luminescence properties of Ce,Cr:LuAG TCs were systematically investigated. The CRI values of Ce:LuAG TC based white LEDs could be increased by a magnitude of 46.2%. Particularly, by combining the as fabricated Ce,Cr:LuAG TCs with a 0.5 at% Ce:YAG TC, surprising CRI values of 88 and 85.5 were obtained in TC based white LEDs and LDs, respectively. Therefore, Ce,Cr:LuAG TC is a highly promising color convertor for high-power white LEDs/LDs applied in general lighting and displaying.
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