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Nanostructured Surfaces
16
Citations
0
References
2001
Year
EngineeringMolecular Self-assemblyNanostructured SurfaceLigand-protected Au55 ClustersSurface NanotechnologyChemistryNanoengineeringMaterials FabricationImprinting MethodHybrid MaterialsMaterials ScienceNanometer RangeNanotechnologyNanomanufacturingNanostructuringSurface NanoengineeringSurface FunctionalizationMicrofabricationNanomaterialsSelf-assemblySurface ScienceNatural SciencesInterfacial PhenomenaNanofabricationNanostructures
Many approaches to the structuring of surfaces in the micrometer and nanometer range have been undertaken in the last few decades. Most of these technologies, however, are limited to the fabrication of small areas. In this article two methods for the creation of larger areas of structured surfaces are discussed. The first approach is based on the self-assembly of ligand-protected Au55 clusters at the phase boundary between water and dichloromethane, with subsequent transfer to a solid substrate. The other strategy employs nanoporous alumina membranes as masks for the imprinting of metal and polymer surfaces. The self-assembly generates surfaces with building blocks of about 2 nm (see Figure) whereas the imprinting method leads to structural units of 10–200 nm.