Efficient near‐infrared pyroxene phosphor LiInGe ₂ O ₆ :Cr ³⁺ for NIR spectroscopy application

Abstract

Abstract Broadband near‐infrared phosphors are essential to realize nondestructive analysis in food industry and biomedical areas. Efficient long‐wavelength (>830 nm) phosphors are strongly desired for practical applications. Herein, we demonstrate an efficient broadband NIR phosphor LiInGe 2 O 6 :Cr 3+ , which exhibits a broad NIR emission peaking at ~880 nm with a full width at half maximum of 172 nm upon 460 nm excitation. The internal/external quantum efficiencies of LiInGe 2 O 6 :Cr 3+ are measured to be 81.2% and 39.8%, respectively. The absorption of the phosphor matches well with commercial blue LEDs. Using the fabricated phosphor converted LED illuminating human palm, distribution of blood vessels can be clearly recognized under a NIR camera. These results indicate that LiInGe 2 O 6 :Cr 3+ is a promising candidate to be used in future non‐destructive biological applications.