Hydroxyapatite Extracted from Fish Bone Wastes by Heat Treatment

Abstract

The present work demonstrates a low-cost route to produce hydroxyapatite (HAp) from fish bones (natural source) by a simple heat-treatment process. The produced HAp was characterized by X-ray Diffraction (XRD) and Fourier Transform Infra-Red (FTIR). Energy Dispersive X-ray (EDX) analysis obtained elemental composition that confirmed the presence of Ca and P; then the Ca/P mole ratio was calculated. XRD analysis from Chanos chanos and Calarias batracus bone has produced the diffraction peaks at 31.8°, 32.1°, and 32.9° that corresponded to the HAp phase. The presence of functional groups, PO 4 3‒ and OH ‒ , has been confirmed by FTIR spectra that arecharacteristics of HAp. EDX analysis has shown that the Ca/P mole ratio was similar to the Ca/P mole ratio of the HAp’s stoichiometry (1.66). But actually, not all fish bones can produce pure HAp after the heat-treatment process, such as Tylosurus crocodilus bone. Based on XRD analysis from the main diffraction peak form is a β-TCP phase