Publication | Open Access
Formal Syntheses of Dihydrocorynantheine and Isorhynchophylline via Proline Catalyzed Mannich-Michael Reaction
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References
2010
Year
EngineeringBiochemistryNatural SciencesDiversity-oriented SynthesisStereoselective Manner.the ReactionMannich-michael ReactionOrganic ChemistryCatalysisFormal SynthesesChemistryStereoselective SynthesisNatural Product SynthesisAsymmetric CatalysisSynthetic ChemistryEnantioselective Synthesis
Proline catalyzed Mannich-Michael reaction of 3-ethyl-3-buten-2-one with 9-tosyl-3,4-dihydro-β-carboline proceeded in a highly stereoselective manner.The reaction was applied to formal syntheses of dihydrocorynantheine and isorhynchophylline.
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