Stereoselective synthesis of both (E)- and (Z)-1,2,4-heptatrien-6-ynes. Formation of an .alpha.,3-dehydrotoluene biradical, trapping by an intramolecular carbon-carbon double bond, and decay of the resulting new biradical via an intramolecular route

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStereoselective synthesis of both (E)- and (Z)-1,2,4-heptatrien-6-ynes. Formation of an .alpha.,3-dehydrotoluene biradical, trapping by an intramolecular carbon-carbon double bond, and decay of the resulting new biradical via an intramolecular routeYemane W. Andemichael, Yu Gui Gu, and Kung K. WangCite this: J. Org. Chem. 1992, 57, 3, 794–796Publication Date (Print):January 1, 1992Publication History Published online1 May 2002Published inissue 1 January 1992https://doi.org/10.1021/jo00029a002RIGHTS & PERMISSIONSArticle Views223Altmetric-Citations36LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (398 KB) Get e-AlertsSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts