Concepedia

Facile Access to Labdane-type Diterpenes: Synthesis of Coronarin C, Zerumin B, Labda-8(17), 13(14)-dien-15,16-olide and derivatives from (+)-manool

José E. Villamizar, Jose I. Juncosa, Jean Pittelaud, M. Hernández, Nieves Canudas, Eleonora Tropper, Franklin Salazar, Juan A. Fuentes

Journal of Chemical Research · 2007 · 11 citations · 12 references

DOI

Concepts

Abstract

A practical method for the synthesis of optically active labdane-type diterpenes from (+)-manool 8, is described. We prepared the natural labdane-type diterpene 5 via key intermediate peroxide 9 and coronarin C 1, compound 8 and zerumin B 6 via a furan photosensitised oxygenation reactions.

References

12

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