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Carbometallation (<i>C</i>-Metallation) of Alkynes: Stereospecific Synthesis of Alkenyl Derivatives

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Organic Chemistry, Alkenyl Derivatives, Stereoselective Synthesis +1

Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins

Ei‐ichi Negishi, Nobuhisa Okukado, Anthony O. King et al. · Journal of the American Chemical Society · 1978 · 304 citations

Chemical Engineering, Cross-coupling Reaction, Engineering +9

Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

David E. Van Horn, Ei‐ichi Negishi · Journal of the American Chemical Society · 1978 · 284 citations

Chemical Engineering, Cross-coupling Reaction, Engineering +10

Bimetallic catalytic systems containing Ti, Zr, Ni, and Pd. Their applications to selective organic syntheses

Ei‐ichi Negishi · Pure and Applied Chemistry · 1981 · 240 citations · Full text

Materials Science, Inorganic Chemistry, Engineering +8