Organic Letters · 2000 · 112 citations · 17 references
Natural SciencesBiochemistryChemistryBiocatalysisCatalysisEnzymologyCatalytic MechanismsCatalytic Reaction KineticsEnzymatic CatalysisEnzyme CatalysisEnzyme KineticsIndustrial CatalysisCatalyst KineticsCatalytic Reaction MechanismsDynamic Kinetic ResolutionEnzyme Catalysis KineticsEnzyme Reaction KineticsKinetic ResolutionLipase CatalysisStereoselective Enzyme Catalysis
An enzyme-metal combo reaction has been developed for the dynamic kinetic resolution of allylic alcohols in which racemic substrates are transformed by a lipase and a ruthenium complex in the presence of an acyl donor to allylic acetates of high optical purity in over 80% yield.
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Catalytic Asymmetric Synthesis.
Ryōji Noyori · Journal of Synthetic Organic Chemistry Japan · 1992 · 809 citations · Full text
Hélène Pellissier · Tetrahedron · 2003 · 561 citations
Robert S. Ward · Tetrahedron Asymmetry · 1995 · 425 citations