Angewandte Chemie International Edition · 2019 · 45 citations · 48 references
Natural SciencesChemistryCatalysisInorganic ChemistrySafer Chemical SynthesisFluorination ProcessesHydrofluorinationIron CatalysisIron-catalyzed OxidationLigand SelectivityTransition-metal-catalyzed Functionalization
An iron-catalyzed hydrofluorination of unactivated alkenes has been developed. The use of a multidentate ligand and the fluorination reagent N-fluorobenzenesulfonimide (NFSI) proved to be critical for this reaction, which afforded various fluorinated compounds in up to 94 % yield.
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Functionalized olefin cross-coupling to construct carbon–carbon bonds
Julian C. Lo, Jinghan Gui, Yuki Yabe et al. · Nature · 2014 · 488 citations
Fe-Catalyzed C–C Bond Construction from Olefins via Radicals
Julian C. Lo, Dongyoung Kim, Chung‐Mao Pan et al. · Journal of the American Chemical Society · 2017 · 432 citations · Full text