Nature Communications · 2019 · 121 citations · 36 references
Natural SciencesChemical EngineeringChemistryBiocatalysisCatalysisReaction EngineeringBiocatalytic StereoselectivityCatalytic MechanismsCatalytic Reaction EngineeringChemical EvolutionHydration EffectsWater ChemistryCatalytic Reaction MechanismsCatalytic Reaction ThermodynamicsChiralityEnantioselective CatalysisEnantioselectivityPrebiotic SelectivityStereoinduction MechanismsWater-mediated Catalysis
The manipulation of the transition states of a chemical process is essential to achieve the desired selectivity. In particular, transition states of chemical reactions can be significantly modified in a confined environment. We report a catalytic reaction with remarkable amplification of stereochemical information in a confined water cage. Surprisingly, this amplification is significantly dependent on droplet size. This water-induced chirality amplification stems from the hydrophobic hydration effects, which ensures high proximity of the catalyst and substrates presumably at the transition state, leading to higher enantioselectivity. Flow and batch reactors were evaluated to confirm the generality of this water-induced chirality amplification. Our observation on efficient chiral induction in confined water cages might lead to an understanding of the chirality amplification in the prebiotic era, which is a key feature for the chemical evolution of homochirality.
36
Asymmetric autocatalysis and amplification of enantiomeric excess of a chiral molecule
Kenso Soai, Takanori Shibata, Hiroshi Morioka et al. · Nature · 1995 · 1.1K citations
On the Theory of Organic Catalysis “on Water”
Yousung Jung, R. A. Marcus · Journal of the American Chemical Society · 2007 · 698 citations