Concepedia

Twisting the arm: structural constraints in bicyclic expanded-ring N-heterocyclic carbenes

Katharine R. Sampford, Jamie L. Carden, Edward B. Kidner, Abigail Berry, K.J. Cavell, Damien M. Murphy, Benson M. Kariuki, Paul D. Newman

Dalton Transactions · 2019 · 19 citations · 53 references

DOIFull text

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Concepts

Abstract

values of the dialkyl derivatives reported here, a feature related to the fixed conformation of the heterocyclic rings and the compressional effect of a pre-set methyl substituent.

References

53

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Crystal structure refinement with<i>SHELXL</i>

George M. Sheldrick · Acta Crystallographica Section C Structural Chemistry · 2014 · 42.5K citations · Full text

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An overview of N-heterocyclic carbenes

Matthew N. Hopkinson, Christian Richter, Michael Schedler et al. · Nature · 2014 · 4.2K citations

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Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

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SambVca 2. A Web Tool for Analyzing Catalytic Pockets with Topographic Steric Maps

Laura Falivene, Raffaele Credendino, Albert Poater et al. · Organometallics · 2016 · 883 citations · Full text

, , +17