Concepedia

Synthesis and reactivity of a PC<sub>carbene</sub>P cobalt(<scp>i</scp>) complex: the missing link in the cobalt PXP pincer series (X = B, C, N)

Simon Sung, Qingyang Wang, Tobias Krämer, Rowan D. Young

Chemical Science · 2018 · 35 citations · 68 references

DOIFull text

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Concepts

Abstract

is found to avoid C-H activation of the proligand, and instead proceeds through a combination of O-H activation, hydrogen atom transfer, β-hydride elimination and hydrogen activation processes.

References

68

Ligand-Controlled Cobalt-Catalyzed Transfer Hydrogenation of Alkynes: Stereodivergent Synthesis of <i>Z</i>- and <i>E-</i>Alkenes

Shaomin Fu, Nan‐Yu Chen, Xufang Liu et al. · Journal of the American Chemical Society · 2016 · 327 citations

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Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex

Arup Mukherjee, Dipankar Srimani, Subrata Chakraborty et al. · Journal of the American Chemical Society · 2015 · 285 citations

, , +16

Cobalt-Catalyzed Acceptorless Alcohol Dehydrogenation: Synthesis of Imines from Alcohols and Amines

Guoqi Zhang, Susan K. Hanson · Organic Letters · 2013 · 267 citations

, , +15

Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation

Hongjian Lu, Wojciech I. Dzik, Xue Xu et al. · Journal of the American Chemical Society · 2011 · 257 citations

, , +12

Boryl-Mediated Reversible H<sub>2</sub> Activation at Cobalt: Catalytic Hydrogenation, Dehydrogenation, and Transfer Hydrogenation

Tzu‐Pin Lin, Jonas C. Peters · Journal of the American Chemical Society · 2013 · 255 citations

, , +16