Evidence for Aggregation-Induced Emission from Free Rotation Restriction of Double Bond at Excited State

Jia‐Bin Xiong, Ying‐Xue Yuan, Lian Wang, Jian-Ping Sun, Weiguo Qiao, Hongchao Zhang, Miao Duan, Hongwei Han, Song Zhang, Yan‐Song Zheng

Organic Letters · 2018 · 137 citations · 26 references

Concepts

Abstract

This paper reports that cis-TPE dicycles emit strong fluorescence, while the gem dicycles show almost no emission in solution, demonstrating that the free rotation restriction of the double bond at the excited state is the key factor for AIE effects.

References

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