Organic Letters · 2018 · 137 citations · 26 references
Natural SciencesChemistryPhysicsBiophysical ChemistryMolecular PhysicsSpectroscopyElectronic Excited StatesEmission SpectroscopyFluorescence SpectroscopyMolecular RotationOptical SpectroscopyPhotochemistryAggregation-induced Emission SensorsDouble Bond ConfigurationExcited-state AbsorptionExcited-state Configurations
This paper reports that cis-TPE dicycles emit strong fluorescence, while the gem dicycles show almost no emission in solution, demonstrating that the free rotation restriction of the double bond at the excited state is the key factor for AIE effects.
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