EU PVSEC · 2017 · 12 citations · 0 references
EngineeringMaterials EngineeringMaterials ScienceElectronic MaterialsSemiconductor DevicesSemiconductor MaterialsPhotovoltaic DevicesSemiconductor Device MaterialsSemiconductor InterfacesSemiconductor SurfacesSolar Cell MaterialsSolar CellsContact FormationCurrent DensityLaser AblationMetallizationPassivation LayersSaturation CurrentSilicon Solar CellsSolar Cell Fabrication
In this work we investigated the metallization process of screen-printed n-type passivated emitter rear totally diffused (n-PERT) rear junction (RJ) silicon solar cells. We used the voltage calibrated photoluminescence (PL) method to extract the saturation current density on the laser ablated surface before metallization (J0-abl) and at the metal-silicon interface after metallization (J0-met). Symmetrically diffused and passivated test samples, printed with specific metallization patterns, were fabricated for this purpose. We investigated the influence on J0-met varying boron (p+) and phosphorous (n+) diffusions, cleaning after laser ablation, metal pastes and peak firing temperature. The optimum parameters were then applied to fabricate n-PERT-RJ cells.