2D Materials · 2017 · 300 citations · 67 references
EngineeringElectrical EngineeringMaterials ScienceElectronic MaterialsMicroelectronicsSemiconductor DevicesCarrier TransportMemory DevicesSemiconductor DefectsSemiconductor InterfacesSemiconductor PhysicsSemiconductor SurfacesBack-gated Field-effect TransistorsCharge TrappingCharge Trapping EffectsHysteresis PhenomenaIntrinsic DefectsLight IntensityTransfer CharacteristicsVacancies
Abstract We investigate the origin of the hysteresis observed in the transfer characteristics of back-gated field-effect transistors with an exfoliated MoS 2 channel. We find that the hysteresis is strongly enhanced by increasing either gate voltage, pressure, temperature or light intensity. Our measurements reveal a step-like behavior of the hysteresis around room temperature, which we explain as water-facilitated charge trapping at the MoS 2 /SiO 2 interface. We conclude that intrinsic defects in MoS 2 , such as S vacancies, which result in effective positive charge trapping, play an important role, besides H 2 O and O 2 adsorbates on the unpassivated device surface. We show that the bistability associated to the hysteresis can be exploited in memory devices.
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