The Journal of Chemical Physics · 2016 · 59 citations · 15 references
Natural SciencesChemistryPhysicsElectromagnetismQuantum ChemistrySpectroscopyBeyond The Standard Model PhysicsElectron CorrelationHyperfine StructureMolecular SymmetryBeyond Standard Model SearchesBeyond The Standard Model Flavor ConstraintsBeyond The Standard Model SearchesDiscrete Symmetry BreakingHyperfine Structure ConstantsHyperfine Structure In Magnetic FieldsStrong Coupling ConstantThorium Chemistry
We present an updated electron electric dipole moment (EDM) effective electric field of Eeff= 75.2 GV/cm and 229Th magnetic hyperfine interaction constant A|| = −1266 MHz, the nucleon-electron scalar-pseudoscalar interaction constant WS = 106.0 kHz, and the molecule-frame static electric dipole moment D = −4.41 D for the Δ13 science state of ThO. The criticisms of the results from Fleig and Nayak [J. Mol. Spectrosc. 300, 16 (2014)] made in Skripnikov and Titov [J. Chem. Phys. 142, 024301 (2015)] are addressed and largely found to be unsubstantiated within the framework of the present approach. The present findings confirm the slightly relaxed constraints on relevant beyond-standard-model parameters, in particular the electron EDM, de, and the nucleon-electron scalar-pseudoscalar coupling constant, CS.
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Natural Sciences, Physics, Cosmology +11