Hierarchical Dendrite-Like Magnetic Materials of Fe₃O₄, γ-Fe₂O₃, and Fe with High Performance of Microwave Absorption

TLDR

Iron‑based microstructured or nanostructured materials, including Fe, γ‑Fe₂O₃, and Fe₃O₄, are highly desirable for magnetic applications because of their high magnetization and a wide range of magnetic anisotropy. An important application of these materials is as electromagnetic wave absorbers to absorb radar waves in the centimeter wave (2–18 GHz). Dendrite‑like microstructures were obtained by phase transformation from dendritic α‑Fe₂O₃ to Fe₃O₄ and Fe via partial and full reduction, and from γ‑Fe₂O₃ via a reduction–oxidation process, while preserving the dendritic morphology. The three hierarchical microstructures are typical ferromagnets and exhibit excellent microwave absorbability, with Fe’s absorption due to dielectric loss and Fe₃O₄/γ‑Fe₂O₃’s absorption arising from combined dielectric and magnetic loss.

Abstract

Iron-based microstructured or nanostructured materials, including Fe, γ-Fe2O3, and Fe3O4, are highly desirable for magnetic applications because of their high magnetization and a wide range of magnetic anisotropy. An important application of these materials is use as an electromagnetic wave absorber to absorb radar waves in the centimeter wave (2−18 GHz). Dendrite-like microstructures were achieved with the phase transformation from dendritic α-Fe2O3 to Fe3O4, Fe by partial and full reduction, and γ-Fe2O3 by a reduction−oxidation process, while still preserving the dendritic morphology. The investigation of the magnetic properties and microwave absorbability reveals that the three hierarchical microstructures are typical ferromagnets and exhibit excellent microwave absorbability. In addition, this also confirms that the microwave absorption properties are ascribed to the dielectric loss for Fe and the combination of dielectric loss and magnetic loss for Fe3O4 and γ-Fe2O3.