Asymmetric synthesis of (R)-ar-curcumene, (R)-4,7-dimethyl-l-tetralone, and their enantiomers via cobalt-catalyzed asymmetric Kumada cross-coupling

Selective carbon-carbon bond formation by cross-coupling of Grignard reagents with organic halides. Catalysis by nickel-phosphine complexes

Kohei Tamao, Koji Sumitani, Makoto Kumada · Journal of the American Chemical Society · 1972 · 1.3K citations

Natural Sciences, Chemistry, Catalysis +12

Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition-metal complexes. 6. Practical asymmetric synthesis of 1,1'-binaphthyls via asymmetric cross-coupling with a chiral [(alkoxyalkyl)ferrocenyl]monophosphine/nickel catalyst

Tamio Hayashi, Keiichi Hayashizaki, Takao Kiyoi et al. · Journal of the American Chemical Society · 1988 · 312 citations

Natural Sciences, Chemistry, Catalysis +10

Nickel/Bis(oxazoline)-Catalyzed Asymmetric Kumada Reactions of Alkyl Electrophiles: Cross-Couplings of Racemic α-Bromoketones

Sha Lou, Gregory C. Fu · Journal of the American Chemical Society · 2010 · 280 citations · Full text

Natural Sciences, Chemistry, Medicinal Chemistry +14

Total synthesis of the polyether antibiotic ionomycin

David A. Evans, Robert L. Dow, Thomas L. Shih et al. · Journal of the American Chemical Society · 1990 · 236 citations

Pharmacy, Medicinal Chemistry, Pharmacology +7

Antimalarial sesquiterpenes from tubers of Cyperus rotundus: structure of 10,12-Peroxycalamenene, a sesquiterpene endoperoxide

Chachanat Thebtaranonth, Yodhathai Thebtaranonth, Sombat Wanauppathamkul et al. · Phytochemistry · 1995 · 176 citations

Life Sciences, Botany, Pharmacology +9