Concepedia

Complexes of {Mo<sub>6</sub>I<sub>8</sub>} with nitrophenolates: synthesis and luminescence

Maksim A. Mikhailov, Konstantin A. Brylev, A.V. Virovets, Marsel R. Gallyamov, Igor N. Novozhilov, Maxim N. Sokolov⧫

New Journal of Chemistry · 2015 · 37 citations · 32 references

DOI

Concepts

Abstract

New bright-red luminescent nitrophenolate complexes (Bu<sub>4</sub>N)<sub>2</sub>[{Mo<sub>6</sub>I<sub>8</sub>}(OR)<sub>6</sub>] (R = C<sub>6</sub>H<sub>4</sub>-<italic>p</italic>-(NO<sub>2</sub>), C<sub>6</sub>H<sub>3</sub>-2,4-(NO<sub>2</sub>)<sub>2</sub>) have been prepared from (Bu<sub>4</sub>N)<sub>2</sub>[{Mo<sub>6</sub>I<sub>8</sub>}I<sub>6</sub>] and AgOR, characterized by X-ray analysis, UV-Vis and IR spectroscopies and ESI-mass spectrometry.

References

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Highly luminescent complexes [Mo6X8(n-C3F7COO)6]2− (X = Br, I)

Maxim N. Sokolov⧫, M.A. Mihailov, Eugenia V. Peresypkina et al. · Dalton Transactions · 2011 · 143 citations

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