Concepedia

Highly luminescent complexes [Mo6X8(n-C3F7COO)6]2− (X = Br, I)

Maxim N. Sokolov⧫, M.A. Mihailov, Eugenia V. Peresypkina, Konstantin A. Brylev, Noboru Kitamura, Vladimir P. Fedin

Dalton Transactions · 2011 · 143 citations · 16 references

DOI

Concepts

Abstract

New complexes (Bu(4)N)(2)[Mo(6)X(8)(n-C(3)F(7)COO)(6)] (X = Br, I) display extraordinarily bright long-lived red phosphorescence both in solution and solid phases, with the highest emission quantum yields and the longest emission lifetimes among hexanuclear metal cluster complexes of Mo, W and Re, hitherto reported.

References

16

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Water‐in‐Oil Microemulsion Preparation and Characterization of Cs<sub>2</sub>[Mo<sub>6</sub>X<sub>14</sub>]@SiO<sub>2</sub> Phosphor Nanoparticles Based on Transition Metal Clusters (X = Cl, Br, and I)

Fabien Grasset, F. Dorson, Stéphane Cordier et al. · Advanced Materials · 2007 · 105 citations · Full text

, , +17