Chemical Communications · 2012 · 128 citations · 32 references
Natural SciencesChemistryCatalysisOrganic ChemistryCatalyst DesignCatalytic MechanismsCross-coupling ReactionsC - H Activation Cross-couplingC-h Bond ActivationCatalytic AcylationCross-coupling CatalysisDecarboxylative CouplingDecarboxylative Cross-couplingPalladium CatalystsPalladium-catalyzed Cross-coupling
A mild, practical and efficient palladium-catalyzed decarboxylative ortho-acylation of O-methyl ketoximes with α-keto acids via C-H bond activation is described. In these reactions, a broad range of O-methyl ketoximes and α-keto acids undergoes the decarboxylative cross-coupling reactions with high selectivities and good tolerance.
32
Synthesis of Biaryls via Catalytic Decarboxylative Coupling
Lukas J. Gooßen, Guo‐Jun Deng, Laura M. Levy · Science · 2006 · 946 citations