Oligonucleotide‐Templated Self‐Assembly of Nucleotide Bolaamphiphiles: DNA‐Like Nanofibers Edged by a Double‐Helical Arrangement of A–T Base Pairs

Rika Iwaura, Kaname Yoshida, Mitsutoshi Masuda, Mayumi Ohnishi‐Kameyama, Mitsuru Yoshida, Toshimi Shimizu

Angewandte Chemie International Edition · 2003 · 137 citations · 36 references

Concepts

Abstract

A stack with a twist is formed when a thymidine bolaamphiphile (green rod with red ends in the scheme) is allowed to interact with strands of oligoadenylic acid (purple chain with yellow pentagons) in aqueous solution. Complementary A–T hydrogen bonding leads to nanofibers having a DNA-like double helix.

References

36