Concepedia

Discovery of a Family of Isopolyoxotungstates [H<sub>4</sub>W<sub>19</sub>O<sub>62</sub>]<sup>6−</sup> Encapsulating a {WO<sub>6</sub>} Moiety within a {W<sub>18</sub>} Dawson‐like Cluster Cage

De‐Liang Long, Paul Kögerler, Alexis D. C. Parenty, John Fielden, Leroy Cronin

Angewandte Chemie International Edition · 2006 · 101 citations · 38 references

DOI

Concepts

Abstract

Caged up: A family of isopolyoxotungstate clusters of the form [H4W19O62]6− with a cluster cage (blue) identical to that of the Dawson-type heteropolyacids (red) has been discovered. These comprise a single trigonal-prismatic or octahedral {WO6}6− moiety in place of the two heteroanions found in the Dawson structure.

References

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