Publication | Closed Access
Concise total syntheses of epothilone A and C based on alkyne metathesis
95
Citations
20
References
2001
Year
Enantioselective SynthesisEngineeringAlkene MetathesisAlkyne MetathesisConcise Total SynthesesNatural SciencesDiversity-oriented SynthesisEpothilone AOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryAsymmetric CatalysisMolybdenum Complex 26Biomolecular EngineeringCycloalkyne Product
A ring closing alkyne metathesis reaction catalyzed by the molybdenum complex 26 followed by a Lindlar reduction of the resulting cycloalkyne product opens an efficient and stereoselective entry into epothilone A and C.
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