Powder diffraction analysis of cerium dioxide at high pressure

L. Gerward, J. Staun Olsen

Powder Diffraction · 1993 · 147 citations · 12 references

Concepts

Abstract

CeO 2 transforms to an orthorhombic PbCl 2 -type structure at a pressure of about 31 GPa. The phase transition is accompanied by a 9.8% volume contraction. The bulk modulus of the low-pressure fluorite-type structure is 236(4) GPa. Comparisons are made with the high-pressure behaviour of UO 2 and ThO 2 .

References

12