Chemical Communications · 2004 · 145 citations · 5 references
EngineeringOrganic ChemistryChemistryBiphasic SystemBioenergeticsBiochemical EngineeringAlcohol DehydrogenasesReductionelectronic Supplementary InformationFavourable PartitionIonic LiquidAldehyde DehydrogenaseBiochemistryBiocatalysisCatalysisDeep Eutectic SolventAsymmetric CatalysisEnantioselective SynthesisBiomolecular EngineeringNatural SciencesEnzyme CatalysisAlcohol DehydrogenaseMolecular Catalysis
Due to favourable partition coefficients the highly enantioselective reduction of 2-octanone, catalysed by an alcohol dehydrogenase from Lactobacillus brevis, is faster in a biphasic system containing buffer and the ionic liquid [BMIM][(CF(3)SO(2))(2)N] compared to the reduction in a biphasic system containing buffer and methyl tert-butyl ether.
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Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts
Pierre Bonhôte, Ana-Paula Dias, N. Papageorgiou et al. · Inorganic Chemistry · 1996 · 4.3K citations · Full text