Chromium(III) catalyzed synthesis of allenes from propargyl derivatives via a carbometalation–elimination sequence

Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

David E. Van Horn, Ei‐ichi Negishi · Journal of the American Chemical Society · 1978 · 284 citations

Natural Sciences, Chemistry, Catalysis +16

Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes

Ei‐ichi Negishi, David E. Van Horn, Tadao Yoshida · Journal of the American Chemical Society · 1985 · 246 citations

Natural Sciences, Chemistry, Catalysis +6

Homogeneous Chromium Catalysts for Olefin Polymerization

Klaus H. Theopold · European Journal of Inorganic Chemistry · 1998 · 242 citations

Natural Sciences, Chemical Engineering, Chemistry +14

Donor-Ligand-Substituted Cyclopentadienylchromium(III) Complexes:  A New Class of Alkene Polymerization Catalyst. 1. Amino-Substituted Systems

A. Döhring, J. Göhre, P.W. Jolly et al. · Organometallics · 2000 · 173 citations

Natural Sciences, Chemistry, Organic Chemistry +13

Controlled carbometalation as a new tool for carbon-carbon bond formation and its application to cyclization

Ei‐ichi Negishi · Accounts of Chemical Research · 1987 · 173 citations

Natural Sciences, Chemistry, Drug Discovery +9