Publication | Closed Access
Cobalt‐Catalyzed Reductive Allylation of Alkyl Halides with Allylic Acetates or Carbonates
143
Citations
36
References
2011
Year
Chemical EngineeringCobalt‐catalyzed Reductive AllylationEngineeringAlkene MetathesisCross-coupling ReactionAlkyl HalidesSimple CobaltOrganic ChemistryOrganometallic CatalysisCatalysisChemistryAllylic AcetatesSubstituted Allylic AcetatesAsymmetric CatalysisDirect AllylationEnantioselective Synthesis
An efficient method for the direct allylation of alkyl halides catalyzed by simple cobalt(II) bromide has been developed. This reaction, using a variety of substituted allylic acetates or carbonates, provides the linear product as the major product. It displays broad substrate scope and good functional group tolerance.
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