Cobalt‐Catalyzed Reductive Allylation of Alkyl Halides with Allylic Acetates or Carbonates

Xin Qian, Audrey Auffrant, Abdellah Felouat, Corinne Gosmini

Angewandte Chemie International Edition · 2011 · 147 citations · 36 references

Concepts

Abstract

An efficient method for the direct allylation of alkyl halides catalyzed by simple cobalt(II) bromide has been developed. This reaction, using a variety of substituted allylic acetates or carbonates, provides the linear product as the major product. It displays broad substrate scope and good functional group tolerance.

References

36