Pressure-induced Raman spectral changes of<i>N</i>,<i>N</i>,diethyl-<i>N</i>-methyl-<i>N</i>-(2-methoxyethyl) ammonium tetrafluoroborate

Abstract

We have measured Raman spectral changes in one of the aliphatic series of ionic liquids, N,N,diethyl-N-methyl-N-(2-methoxyethyl) ammonium tetrafluoroborate, [DEME][BF4], under high pressure. Although the [DEME] cation has mainly two stable conformers of TG +−tg + t and TG +−g + g − t in the liquid state, the population of the minor conformer, i.e. TG +−g + g − t, decreases with increasing pressure. The difference in the partial molar volume between the two conformers was determined from the pressure dependence of the relative Raman intensity ratio.