Concepedia

Methylation of arenes via Ni-catalyzed aryl C–O/F activation

Bing‐Tao Guan, Shi‐Kai Xiang, Tao Wu, Zuo‐Peng Sun, Bi‐Qin Wang, Ke‐Qing Zhao, Zhang‐Jie Shi

Chemical Communications · 2008 · 212 citations · 22 references

DOI

Concepts

Abstract

Aryl C-O and C-F can be transformed into C-Me via Ni-catalyzed coupling with MeMgBr under mild conditions.

References

22

Catalytic C−C Bond Formation Accomplished by Selective C−F Activation of Perfluorinated Arenes

Thomas Schaub, Marc Backes, Udo Radius · Journal of the American Chemical Society · 2006 · 390 citations

, , +16

Nickel‐Catalyzed Cross‐Coupling of Aryl Grignard Reagents with Aromatic Alkyl Ethers: An Efficient Synthesis of Unsymmetrical Biaryls

John W. Dankwardt · Angewandte Chemie International Edition · 2004 · 303 citations

, , +13

Ruthenium-Catalyzed Functionalization of Aryl Carbon−Oxygen Bonds in Aromatic Ethers with Organoboron Compounds

Fumitoshi Kakiuchi, Mayumi Usui, Satoshi Ueno et al. · Journal of the American Chemical Society · 2004 · 253 citations

, , +11

Transformation of carbon-oxygen into carbon-carbon bonds mediated by low-valent nickel species

Ernest Wenkert, Enrique L. Michelotti, Charles S. Swindell et al. · The Journal of Organic Chemistry · 1984 · 239 citations

, , +6

Low-Valent Niobium-Mediated Double Activation of C−F/C−H Bonds:  Fluorene Synthesis from <i>o</i>-Arylated α,α,α-Trifluorotoluene Derivatives

Kohei Fuchibe, Takahiko Akiyama · Journal of the American Chemical Society · 2006 · 183 citations

, , +5