Concepedia

An approach to the preparation of glycosyl phosphates using salicylchlorophosphite as the phosphitylating reagent

J. P. G. Hermans, Erik de Vroom, C. J. J. Elie, G.A. van der Marel, Jacques H. van Boom

Recueil des Travaux Chimiques des Pays-Bas · 1986 · 18 citations · 9 references

DOI

Concepts

Abstract

Abstract The reagent 2‐chloro‐5,6‐benzo‐1,3,2‐dioxaphosphin‐4‐one proved to be suitable for the preparation of an anomerically (α) pure hydrogenphosphonate as well as a phosphite‐triester. The former could be applied for the formation of an interglycosidic hydrogenphosphonate linkage.

References

9

Nucleoside h-phosphonates: Valuable intermediates in the synthesis of deoxyoligonucleotides

Brian C. Froehler, Mark D. Matteucci · Tetrahedron Letters · 1986 · 185 citations

, , +10

A new and versatile approach to the preparation of valuable deoxynucleoside 3′-phosphite intermediates

J. E. MARUGG, A. BURIK, M. Tromp et al. · Tetrahedron Letters · 1986 · 65 citations

, , +4

An approach to the synthesis of α-l-fucopyranosyl phosphoric mono- and diesters via phosphite intermediates

Pieter Westerduin, G.H. Veeneman, J. E. MARUGG et al. · Tetrahedron Letters · 1986 · 60 citations

, , +5

Synthesis of phosphatidyl-α-glucosyl glycerol containing a dioleoyl phosphatidyl moiety. Application of the tetraisopropyldisiloxane-1,3-diyl (tips) protecting group in sugar chemistry. part III

C. A. A. VAN BOECKEL, Jacques H. van Boom · Tetrahedron · 1985 · 42 citations

, , +13

The synthesis of phosphite analogues of ribonucleotides

Kelvin K. Ogilvie, Mona J. Nemer · Tetrahedron Letters · 1980 · 24 citations

, , +12