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Natural selective 2H labelling applied to the study of chemical mechanisms; labelling without enrichment
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1982
Year
Chemical MechanismsBioorganic ChemistryEngineeringChemical AnalysisMolecular BiologySelective EnrichmentChemistryChemical BiologyInternal Distribution DeuteriumGas ChromatographyAnalytical ChemistryStatistical DistributionMolecular RecognitionChromatographyBiochemistryNuclear ReactionsNatural SciencesMass SpectrometryRadioanalytical ChemistryNatural Selective 2HChemical ProbeChemical KineticsMolecular FragmentationDrug Analysis
It is shown that the internal distribution deuterium may considerably differ from the statistical distribution and that this property is exploitable, by quantitative 2H n.m.r. measurements, for investigating reaction mechanisms using isotopic labeling without the need for selective enrichment.