Concepedia

Unmasking Representative Structures of TMP‐Active Hauser and Turbo‐Hauser Bases

Pablo García‐Álvarez, David V. Graham, Eva Hevia, Alan R. Kennedy, J. Klett, Robert E. Mulvey, Charles T. O’Hara, S. Weatherstone

Angewandte Chemie International Edition · 2008 · 125 citations · 19 references

DOI

Abstract

The molecular engines that drive enhanced magnesiations are unveiled through structural elucidation of a 2,2,6,6-tetramethylpiperidide (TMP) Hauser base and its turbo model (see structure; Mg green, Li violet, C purple, O red, N blue, Cl yellow).

References

19

The Cambridge Structural Database: a quarter of a million crystal structures and rising

Frank H. Allen · Acta Crystallographica Section B Structural Science · 2002 · 10.3K citations

, , +16

A LiCl‐Mediated Br/Mg Exchange Reaction for the Preparation of Functionalized Aryl‐ and Heteroarylmagnesium Compounds from Organic Bromides

Arkady Krasovskiy, Paul Knochel · Angewandte Chemie International Edition · 2004 · 906 citations

, , +17

Mixed Mg/Li Amides of the Type R<sub>2</sub>NMgCl⋅LiCl as Highly Efficient Bases for the Regioselective Generation of Functionalized Aryl and Heteroaryl Magnesium Compounds

Arkady Krasovskiy, Valeria Krasovskaya, Paul Knochel · Angewandte Chemie International Edition · 2006 · 501 citations · Full text

, , +17

(tmp)<sub>2</sub>Zn⋅2 MgCl<sub>2</sub>⋅2 LiCl: A Chemoselective Base for the Directed Zincation of Sensitive Arenes and Heteroarenes

Stefan H. Wunderlich, Paul Knochel · Angewandte Chemie International Edition · 2007 · 275 citations

, , +13

Magnesium amide bases and amido-Grignards. 1. Ortho magnesiation

Philip E. Eaton, Chih Hung Lee, Yusheng Xiong · Journal of the American Chemical Society · 1989 · 229 citations

, , +9