Cobalt(II)-Nitronyl Nitroxide Chains as Molecular Magnetic Nanowires

Andréa Caneschi, Dante Gatteschi, N. Lalioti, Claudio Sangregorio, Roberta Sessoli, G. Venturi, Alessandro Vindigni, A. Rettori, M. G. Pini, Miguel A. Novak

Angewandte Chemie International Edition · 2001 · 1.1K citations · 13 references

DOIFull text

Open access

Concepts

Abstract

Slow magnetic relaxation and hysteresis effects of dynamic origin have been observed above liquid helium temperature in a chain compound (see picture), comprising CoII centers and organic radicals, without any evidence of phase transition to three-dimensional magnetic order. These results are the first evidence of the slow dynamics predicted for one-dimensional magnetic systems with Ising anisotropy, and they open the possibility of storing information in a single magnetic nanowire.

References

13