Nanotechnology · 2007 · 775 citations · 28 references
Natural SciencesMaterials EngineeringMaterials ScienceElectronic MaterialsNanomaterialsNanotechnologyFabrication MaterialsOrganic SemiconductorsPolymer ProcessingPolymer Thin FilmsSoft LithographyThin Film LithographyFlexible ElectronicsFlexible SubstratesLarge-area ElectronicsMetal NanoparticlesNanoparticlesOrganic Field-effect TransistorsSubstrate PatterningThermal Control
All-printed electronics is the key technology to ultra-low-cost, large-area electronics. As a critical step in this direction, we demonstrate that laser sintering of inkjet-printed metal nanoparticles enables low-temperature metal deposition as well as high-resolution patterning to overcome the resolution limitation of the current inkjet direct writing processes. To demonstrate this process combined with the implementation of air-stable carboxylate-functionalized polythiophenes, high-resolution organic transistors were fabricated in ambient pressure and room temperature without utilizing any photolithographic steps or requiring a vacuum deposition process. Local thermal control of the laser sintering process could minimize the heat-affected zone and the thermal damage to the substrate and further enhance the resolution of the process. This local nanoparticle deposition and energy coupling enable an environmentally friendly and cost-effective process as well as a low-temperature manufacturing sequence to realize large-area, flexible electronics on polymer substrates.
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Capillary flow as the cause of ring stains from dried liquid drops
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Size effect on the melting temperature of gold particles
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High-Resolution Inkjet Printing of All-Polymer Transistor Circuits
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