A rare ligand bridged ferromagnetically coupled MnIV3 complex with a ground spin state of S = 9/2

Thushan Pathmalingam, Serge I. Gorelsky, T.J. Burchell, Anne‐Catherine Bédard, André M. Beauchemin, Rodolphe Clérac, Muralee Murugesu

Chemical Communications · 2008 · 30 citations · 16 references

Concepts

Abstract

An exclusively chelating ligand bridged high-valent [MnIV3] complex has been synthesized, in which all Mn(IV) ions are ferromagnetically-coupled to exhibit an S(T) = 9/2 spin ground state.

References

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