A Ferromagnetically Coupled Mn₁₉ Aggregate with a Record <i>S</i>=83/2 Ground Spin State

Abstract

Mixing it up: A ground spin state of S=83/2 is found in the mixed-valent manganese aggregate [MnIII12MnII7(μ4-O)8(μ3,η1-N3)8(HL)12(MeCN)6]2+ (H3L=2,6-bis(hydroxymethyl)-4-methylphenol; see polyhedral representation of the core) and arises through ferromagnetic coupling of all the metal centers. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z601467_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.