Concepedia

A Record Anisotropy Barrier for a Single-Molecule Magnet

Constantinos J. Milios, A. Vinslava, Wolfgang Wernsdorfer, Stephen A. Moggach, Simon Parsons, Spyros P. Perlepes, George Christou, Euan K. Brechin

Journal of the American Chemical Society · 2007 · 735 citations · 3 references

DOI

Concepts

Abstract

Structural distortion in a [Mn 6 ] complex switches the magnetic exchange from antiferro- to ferromagnetic, resulting in a single-molecule magnet with a record anisotropy barrier.

References

3

Chemistry and Physics of Supramolecular Magnetic Materials

Olivier Kahn · Accounts of Chemical Research · 2000 · 689 citations

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The Properties of the [Mn<sub>12</sub>O<sub>12</sub>(O<sub>2</sub>CR)<sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>] Single-Molecule Magnets in Truly Axial Symmetry:  [Mn<sub>12</sub>O<sub>12</sub>(O<sub>2</sub>CCH<sub>2</sub>Br)<sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>]·4CH<sub>2</sub>Cl<sub>2</sub>

N.E. Chakov, Sheng-Chiang Lee, Andrew Harter et al. · Journal of the American Chemical Society · 2006 · 163 citations

, , +17

Oxalate-based 2D magnets: the series [NBu<sub>4</sub>][M<sup>II</sup>Mn<sup>III</sup>(ox)<sub>3</sub>] (M<sup>II</sup>= Fe, Co, Ni, Zn; ox = oxalate dianion)

Eugenio Coronado, José Ramón Galán‐Mascarós, Carlos Martí‐Gastaldo · Journal of Materials Chemistry · 2006 · 110 citations

, , +17