Journal of The Electrochemical Society · 1973 · 145 citations · 0 references
Natural SciencesChemistryPhysicsInorganic ChemistryMaterials ChemistrySpectroscopyChemical BondingCoordination ChemistryFluorescence SpectroscopyLuminescent MaterialsMetal-ligand BondingMolecular Orbital TheoryBondingElectronic Structure Of Metal ComplexesEmission SpectraEmission Spectra AnalysisFluorescence Emission SpectraFluorine ChemistryLuminescent Coordination CompoundsManganese Chemistry
The efficiency of Mn(IV) luminescence in fluorine coordination is discussed in the context of the chemical bonding in the center. It is possible that the lower degree of σ‐antibonding in the orbitals, and the greater degree of π‐antibonding in the orbitals, compared with the effect observed in oxides, contributes to a high efficiency and quenching temperature of the emission. The excitation and emission spectra of Mn(IV) in , , and are presented and compared.