Magnetic anisotropy of endohedral lanthanide ions: paramagnetic NMR study of MSc₂N@C₈₀-I_h with M running through the whole 4f row

Abstract

C signals are also considerable. Point charge computations of the ligand field splitting are performed to explain experimental results, and showed reasonable agreement with experimental pseudocontact shifts. Nitrogen atom bearing large negative charge and located close to the lanthanide ion results in large magnetic anisotropy of lanthanide ions in nitride clusterfullerenes with quasi-uniaxial ligand field.