Concepedia

Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

Luca Pignataro, Benita Lynikaite, Raffaele Colombo, Stefano Carboni, Martin Krupička, Umberto Piarulli, Cesare Gennari

Chemical Communications · 2009 · 30 citations · 14 references

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Abstract

Heteroleptic complexes, formed selectively by using a 1 : 1 combination of a sigma-donor and a pi-acceptor ligand, are involved in Rh- and Pd-catalysed reactions.

References

14

Density-functional thermochemistry. III. The role of exact exchange

Axel D. Becke · The Journal of Chemical Physics · 1993 · 102.8K citations

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Highly Enantioselective Rhodium-Catalyzed Hydrogenation with Monodentate Ligands

Michel van den Berg, Adriaan J. Minnaard, Ebe P. Schudde et al. · Journal of the American Chemical Society · 2000 · 435 citations · Full text

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Highly Enantioselective Rh-Catalyzed Hydrogenation Reactions Based on Chiral Monophosphite Ligands

Manfred T. Reetz, Gerlinde Mehler · Angewandte Chemie International Edition · 2000 · 371 citations

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A New Principle in Combinatorial Asymmetric Transition‐Metal Catalysis: Mixtures of Chiral Monodentate P Ligands

Manfred T. Reetz, Thorsten Sell, Andreas Meiswinkel et al. · Angewandte Chemie International Edition · 2003 · 256 citations · Full text

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Chiral monodentate phosphorus ligands for rhodium-catalyzed asymmetric hydrogenation

Thomas Jerphagnon, Jean‐Luc Renaud, Christian Bruneau · Tetrahedron Asymmetry · 2004 · 214 citations

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