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Highly Enantioselective Rh-Catalyzed Hydrogenation Reactions Based on Chiral Monophosphite Ligands
371
Citations
9
References
2000
Year
Chemical EngineeringEnantioselective SynthesisEngineeringRh-catalyzed HydrogenationAlkene MetathesisOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryHomogeneous CatalysisMonophosphites 1Asymmetric CatalysisExcellent LigandsChiral Monophosphite LigandsBiomolecular Engineering
Excellent ligands in the Rh-catalyzed hydrogenation of olefins (ee>95 %) are the monophosphites 1 derived from BINOL. Thus, the notion that only chelating ligands lead to high enantioselectivities in these reactions no longer pertains.
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